Intergranular corrosion facts and how to reduce the risk. Intercrystalline corrosion cracking of power equipment made of. When cracking was first recognized in the application of cu to 4000 series. Duplex stainless steel welds and their susceptibility to intergranular corrosion b. Biddle 3 1arv offshore, 19962 landco building, vipavadeerangsit road samsaennai, phayathai, bangkok 10400, thailand. Mti received five stainless steel bolts from a marine environment.
Dec 23, 2018 in the process of intergranular corrosion, a knifelike attack, a form of intergranular corrosion, can occur when carbon reacts with niobium, titanium or the austenitic stainless steels. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Pdf on aug 5, 2001, ulla ehrnsten and others published intergranular cracking of aisi 316ng stainless steel in bwr environment find, read and cite all the. Forensic failure analysis, corrosion investigation, metallurgical testing and engineering. Nov 21, 2018 an illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. Intergranular fracture occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. Intergranular stress corrosion cracking of austenitic. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Briant, grain boundary segregation of phosphorus and sulfur in type 304 and 316l stainless steel and its effect on intergranular corrosion in the huey test, metal. Sensitised austenitic stainless steel microstructure. This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. Michel ceadender cen cadarache 108 st paul lez durance cedex france abstract over the past years, failure due to heat affected zone stress relief or reheat cracking in austenitic stainless.
Transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use geothermal water heating applications m. Transgranular stress corrosion cracking an overview. Three different materials were subjected to varying heat treatments selected on the basis of fracture characteristics. Intergranular stress corrosion cracking an overview. Characterization of intergranular stress corrosion cracking of 304. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. European corrosion congress eurocorr 2017 and 20th international corrosion congress and process safety congress 2017. Intergranular stress corrosion cracking resistance of. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the. The interaction of corrosion fatigue and stresscorrosion. Gooch introduction although austenitic stainless steels. Transgranular stress corrosion cracking of 304l stainless. So, a stainless steel corrosion can not have all media.
The exact degree to which any of these alloys is resistant to any form of corrosion or stress corrosion depends upon its composition, microstructure, and the exact nature of the solution and solution temperature to which it is. Jul 18, 2008 nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. A stress corrosion crack was grown through a volume of sensitized austenitic stainless steel mapped with dct. An illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. The objective of the programme on mitigation of intergranular stress corrosion cracking in rbmk reactors was to assist rbmk operating countries in mitigating igscc in austenitic stainless steel piping, emphasizing four technical areas. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Metal corrosion, according to management mechanism can be divided into special corrosion, chemical corrosion and electrochemical corrosion of metal corrosion in engineering practice, most belong to electrochemical corrosion. Igscc of bwr low carbon and stabilized stainless steels, late 1980s. Alalloys, ii where stress has a comparatively minor role e. Olson boise state university 1910 university drive boise, idaho 837252075 l. Grain boundary precipitation, notably chromium carbides in stainless steels, is a well recognized and accepted mechanism of intergranular corrosion. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steel electrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Intergranular stress corrosion crack propagation in. Intergranular stress corrosion cracking of welded steel twi. The profound role of the environment chemistry in pitting cracking susceptibility is relevant also for the incidents of the pitting and cracking of stripping columns for a polymer processing plant that were constructed from a few highly corrosion resistant alloys viz.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Hydrogen cracking in metastable austenitic stainless steels. Chromium carbides can be precipitated if the stainless steel is sensitized in the temperature range 550850c 10201560f, for example during heat treatment or welding. On the stress corrosion cracking and hydrogen embrittlement.
The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. The consequence of igo and the concentration gradients that develop during oxide formation is that the material adjacent to the oxides has modified transformational behavior. Sensitization, intergranular attack, stress corrosion. Its mechanical properties enable its structures to remain extremely resistant to rust. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Duplex stainless steel welds and their susceptibility to. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. The main form of corrosion of stainless steel corrosion surface corrosion, pitting corrosion.
Dec 19, 2019 intergranular corrosion occurs in certain grades of stainless steel when the steel is heated, as in welding. The precipitation of chromium carbides consumed the alloying element chromium from a narrow band along the grain boundary and this makes the zone anodic to the unaffected grains. Intergranular stress corrosion cracking has occurred in bwr environments in nonsensitised, coldworked austenitic stainless steel materials. Stress corrosion cracking of an austenitic stainless steel in. Intergranular oxidation igo intergranular attack iga. Chromium carbides can be precipitated if the stainless steel is sensitized in the temperature range 550850c. Consequently, intergranular cracking observed at the lower temperature, that is, 408 k for type 304 and 316 steels is due to grain boundary martensiteinduced hydrogen embrittlement he and transgranular cracking for type 304 and 316 steels at higher temperatures at 416 and 428 k and for 310 steel is ascribed to stress corrosion cracking in.
Scc usually occurs in certain specific alloyenvironmentstress combinations. Nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. Intergranular fracture can occur in a wide variety of materials, including steel alloys, copper alloys, aluminum alloys, and ceramics. Stress corrosion cracking is to bear the stress of the alloy in the corrosive environment because of strong expansion of the alternate failure pattern of a generic term. Fracture of wt% chromium steel blades has been observed to occur in the intergranular mode in certain service failures. Evaluation of grain boundary network and improvement of. But there are ways to mninimize the risk of corrosion. Observations of intergranular stress corrosion cracking in. Carbides form in the areas close the welded part, making it difficult for them to diffuse. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Intergranular attack of steel by molten copper depending on the composition and crystal structure of steel being surfaced with copper, stresses resulting from surfacing under a welding arc together with cu penetration of steel grain boundaries can result in open cracks of significant size under the cu deposit. Decoupling the role of stress and corrosion in the intergranular. However, with modern steel making methods, it has become possible.
Intergranular stresscorrosion cracking igscc is a form of. Chloride stress corrosion cracking in austenitic stainless. Forensic failure analysis, corrosion investigation, metallurgical testing and engineering located in mooresville, nc. Microscopic intergranular cracking was found in several other welds, ie i a weld in lean grade steel, nwb6, consisting of two passes and made with 140c interpass temperature, and ii five welds in high grade steel, nwa3, nwa5, nwa6 and nwa7, ie all welds except single pass weld nwa1 and nwa4, which was made with two passes and 20c. Scc in a 316 stainless steel chemical processing piping system. Analysis of corroded stainless steel bolts summary. Intergranular corrosion stainless steel tubing manufacturer. Recognize the mechanism for igscc and the conditions that make igscc more likely. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Intergranular fracture in wt% chromium martensitic. For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts that have been welded. Influence of chromium depletion on intergranular stress. Fully intergranular cracking was obtained in the 20% deformed, nonsensitised aisi 316ng stainless steel in simulated bwrenvironment.
Intergranular corrosion of stainless steel tubes corrosion resistant. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. The passivity of stainless steel is resulted by availability of a corrosion resistant oxide layer on the surface. Improvements in inservice inspection performance and qualification comprehensive assessment techniques.
Intergranular stress corrosion cracking of austenitic stainless steels. These practices include five intergranular corrosion tests, namely. Hurley boise state university 1910 university drive boise, idaho 837252075 c. T1 intergranular stress corrosion cracking of austenitic stainless steels. The crack growth data and the mechanism are discussed based. In high chloride concentrations like in marine water or in reducing solution, a. As an analogy, in a wall of bricks, intergranular fracture would correspond to a fracture that takes place in the mortar that keeps the bricks. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted fatigue.
Brittleness results, causing the metal to crack near the weld. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion. The photos above show the microstructure of a type 304 stainless steel. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions.
Stainless steel corrosion pitting corrosion crevice. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Stainless steels fine layer of chromium oxide has natural techniques to selfrepair when breached or broken. Intergranular attack in welded stresscorrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. The more commonly seen transgranular fracture, occurs when the crack grows through the material grains. Chloride stress corrosion is a type of intergranular. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Pdf detection and characterisation of intergranular stress. Stainless steels are more resistant to general corrosion compared with carbon steel. The intergranular stress corrosion cracking of sensitized 304 stainless steel in na2s2o3 solutionwas detected by electrochemical noise en. Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking.
With austenitic stainless steels, intergranular attack is usually the result of chromium carbide precipitation cr23c6 at grain boundaries, which produces a narrow zone of chromium depletion at the grain boundary. Igo is a surface phenomenon that is most often associated with atmosphere gas carburizing fig. Chloride scc is intergranular corrosion and occurs in austenitic stainless steel. Fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel. A stress corrosion crack was grown through a volume of sensitized austenitic stainless steel mapped with dct and. Intergranular attack in welded stresscorrosion resistant. Standard practices for detecting susceptibility to. Intergranular corrosion occurs in certain grades of stainless steel when the steel is heated, as in welding. Intergranular stresscorrosion cracking igscc on a sensitized type aisi 304 stainless steel specimen was monitored simultaneously by acoustic emission, elongation measurements, electrochemical. Stress corrosion cracking of an austenitic stainless steel. It is clear that in both cases, cracking occurs at many locations. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. An attempt has been made in this study to identify the conditions in respect of material, loading and environment which may lead to intergranular fracture. Transgranular, granulated, and intergranular stress corrosion.
In practice there are many examples of intergranular cracking, including cases i that depend strongly on stress e. Failure analysis of corrosion on stainless steel fasteners. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. Hydrogen cracking in metastable austenitic stainless. Pdf intergranular cracking of aisi 316ng stainless steel. This form of corrosion occurs at high temperature in the presence of chloride ions and oxygen. In the process of intergranular corrosion, a knifelike attack, a form of intergranular corrosion, can occur when carbon reacts with niobium, titanium or the austenitic stainless steels. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking.
An intergranular attack is caused by the segregation of impurities at the grain boundaries or by enrichment or depletion of one of the alloying elements in the grain boundary areas. The bolts exhibited corrosion predominantly on the head of the bolt around the set screw, underneath the head of the bolt, and in the threads. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Because the solubility of nitrogen is low in the ferritic crystal structure, the precipitates that cause sensitization in ferritic grades include both chromium carbides cr23c6 and chromium. In high chloride concentrations like in marine water or in reducing solution, a variation in active state often occurs. Pdf intergranular cracking of aisi 316ng stainless steel in. Observations of intergranular stress corrosion cracking in a. Although intergranular attack of ferritic stainless steels is similar to that found in austenitic stainless steels, there are some important differences. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
Intergranular attack is caused by the formation of chromium carbides fe,cr23c6 at grain boundaries, reducing the chromium content and the stability of the passive layer on stainless steels. Cracking of stainless steel nozzle sleeve metallurgical. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Pdf intergranular cracking of aisi 316ng stainless steel in bwr. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance, the mechanism involved. Intergranular cracking resistance of the alloy 182 reduces with precipitation of crcarbides due to crdepletion at the grain boundaries in hightemperature oxygenated water 81. Detection and characterisation of intergranular stress.
In many natural conditions, they remain in the passive form and act as cathode to iron or steel. Transgranular, granulated, and intergranular stress. This specification covers the standard practices for detecting susceptibility to intergranular attack in austenitic stainless steels. Inter granular corrosion can be detected by ultrasonic and eddy current methods. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Intergranular corrosion igc intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. During heat treatment certain conditions can cause a material to become susceptible to intergranular attack a. Intergranular stress corrosion cracking scc of pipelines has been known to cause.
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